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Electrically driven thermal light emission from individual single-walled carbon nanotubes

机译:单个单壁的电驱动热光发射   碳纳米管

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摘要

Light emission from nanostructures exhibits rich quantum effects and hasbroad applications. Single-walled carbon nanotubes (SWNTs) are one-dimensional(1D) metals or semiconductors, in which large number of electronic states in anarrow range of energies, known as van Hove singularities, can lead to strongspectral transitions. Photoluminescence and electroluminescence involvinginterband transitions and excitons have been observed in semiconducting SWNTs,but are not expected in metallic tubes due to non-radiative relaxations. Here,we show that in the negative differential conductance regime, a suspendedquasi-metallic SWNT (QM-SWNT) emits light due to joule-heating, displayingstrong peaks in the visible and infrared corresponding to interbandtransitions. This is a result of thermal light emission in 1D, in starkcontrast with featureless blackbody-like emission observed in large bundles ofSWNTs or multi-walled nanotubes. This allows for probing of the electronictemperature and non-equilibrium hot optical phonons in joule-heated QM-SWNTs.
机译:纳米结构的发光表现出丰富的量子效应,具有广阔的应用前景。单壁碳纳米管(SWNT)是一维(1D)金属或半导体,其中在窄能量范围内的大量电子态(称为van Hove奇异点)可导致强光谱跃迁。在半导体单壁碳纳米管中已经观察到涉及带间跃迁和激子的光致发光和电致发光,但由于非辐射弛豫,在金属管中并未出现这种现象。在这里,我们表明,在负差分电导状态下,悬浮的准金属SWNT(QM-SWNT)由于焦耳热而发光,在可见光和红外光中显示出与带间跃迁相对应的强峰。这是一维热发射的结果,与在大束SWNT或多壁纳米管中观察到的无特征的黑体状发射形成鲜明对比。这允许探测焦耳加热的QM-SWNT中的电子温度和非平衡热光子。

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